Gauss' Theorema egregium says that
the Gaussian curvature of a surface can be determined entirely by measuring angles, distances and their rates on the surface itself.
A surface looks like $\mathbb{R}^2$ locally so the angle sum of arbitrarily small triangles tends to $\pi$, doesn't it? Only when one considers bigger triangles - as Gauss did - one will find angle sums deviating from $\pi$. So I wonder how - concretely - an inhabitant of an arbitrarily (but smoothly) curved surface would measure the Gaussian curvature at a given point.