It is known that $P \in B(H)$ is an orthogonal projection if and only if $P^2 = P^* = P$.
Assume $V \perp W$. Then clearly $P_VP_W = P_WP_V =0$
We have $$(P_W + P_V)^2 = P_W^2 + P_WP_V + P_VP_W + P_V^2 = P_W + P_V$$
so $P_W + P_V$ is idempotent. Also $(P_W + P_V)^* =P_W^* + P_V^* = P_W + P_V$ so $P_W + P_V$ is self-adjoint, so we conclude that it is an orthogonal projection.
Conversely, assume that $P_W + P_V$ is an orthogonal projection. Then
$$P_W + P_V = (P_W + P_V)^2 = P_W^2 + P_WP_V + P_VP_W + P_V^2 = P_W + P_WP_V + P_VP_W + P_V$$
which implies $P_WP_V = -P_VP_W$.
Multiplying this from the right by $P_V$ gives $P_WP_V = - P_VP_WP_V$ so
$$P_V(P_WP_V) = -P_WP_V \implies P_WP_V = 0$$
using the hint.
Finally, for $x \in V$ we have
$$ 0 =P_WP_Vx = P_Wx \implies x \perp W$$
so $V \perp W$.