General case for a diagonizable matrix
$$S = U.\Lambda.U^{-1} =
\begin{pmatrix} 3 & 1 \\ 0 & 2 \end{pmatrix}
=\begin{pmatrix} 1 & -1 / \sqrt 2 \\
0 & 1 / \sqrt 2 \end{pmatrix}
\begin{pmatrix} 3 & 0 \\ 0 & 2 \end{pmatrix}
\begin{pmatrix} 1 & 1 \\ 0 & \sqrt 2 \end{pmatrix}$$
Multiplying by $S$ is equivalent to multiplying successively by $U^{-1}$, $\Lambda$ and $U$.
Matrix $U$ is made of columns which are the eigenvectors of $S$. Multiplying by $U^{-1}$ aligns the eigenvectors with the basis vectors.
Scaling by $\Lambda$ preserves the orientation of the eigenvectors, as they are aligned with the basis.
The scaled, but with unchanged orientation, eigenvectors are returned to their initial orientation by multiplying by $U$.

The eigenvectors:
$$v1=\begin{pmatrix} 1 \\ 0 \end{pmatrix} \text { and } v2=\begin{pmatrix} -1 / \sqrt 2 \\ 1 / \sqrt 2 \end{pmatrix}$$
are shown in color.
Specific case of a symmetric matrix
In the case of a real symmetric matrix $S$, $U$ is orthogonal. $U^{-1}=U^T$ and the relationship can be written:
$$S = U.\Lambda.U^T$$
$U$ is a unitary matrix, in the general case, a rotation matrix.
$$ S = \begin{pmatrix} 3 & \sqrt 2 \\ \sqrt 2 & 2 \end{pmatrix}
=\begin{pmatrix} \sqrt {2/3} & -1 / \sqrt 3 \\ 1 / \sqrt 3 & \sqrt {2/3} \end{pmatrix} \begin{pmatrix} 4 & 0 \\ 0 & 1 \end{pmatrix} \begin{pmatrix} \sqrt {2/3} & 1 / \sqrt 3 \\ -1 / \sqrt 3 & \sqrt {2/3} \end{pmatrix} $$

Does this imply that multiplying by any symmetric matrix $S$ is just a scaling by its eigenvalues.
Yes, but as shown, the scaling must be applied in the basis defined by the eigenvectors, or equivalently the basis can be changed prior to apply it. In the case of a real symmetric matrix, the eigenvectors are orthogonal.