If, as is usual, we set
$z = x + iy, \tag 1$
then of course
$e^z = e^{x + iy} = e^x e^{iy} = e^x(\cos y + i\sin y), \tag 2$
which may be written as the mapping
$f:\Bbb R^2 \to \Bbb R^2 \tag 3$
defined by
$f(x, y) = (e^x \cos y, e^x \sin y) = e^x(\cos y, \sin y). \tag 4$
Now if
$e^{z_1} = e^{z_2}, \tag 5$
then
$e^{z_1 - z_2} = 1 \Longrightarrow z_1 - z_2 = 2 \pi i; \tag 6$
it is now easier to make further progress if we switch to the coordinate representation (1) of the complex numbers $z_1, z_2$, since we need specific information concerning tge $y_i$; in these $xy$-coordinates, we see that (6) yields
$(x_1 - x_2) + i(y_1 - y_2) = (x_1 + i y_1) - (x_2 + i y_2) = z_1 - z_2 = 2 \pi i$
$\Longrightarrow x_1 - x_2 = 0, \; y_1 - y_2 = 2 n \pi, \; n \in \Bbb Z, \tag 7$
whence
$x_1 = x_2, \tag 8$
and now it is easy to see that, with $0 < y_1, y_2 < 2\pi$, the only $n \in \Bbb Z$ such that (7) binds is $0$, so
$y_1 = y_2 \tag 9$
as well. So we see that in fact $e^z$ is injective.
Of course, we may also work directly from the form (4) and write
$e^{x_1}(\cos y_1, \sin y_1) = e^{x_2}(\cos y_2, \sin y_2 \Longrightarrow e^{2x_1}(\cos^2 y_1 + \sin^2 y_1) = e^{2x_2} (\cos^2 y_2 + \sin^2 y_2 )$
$\Longrightarrow e^{2 x_1} = e^{2 x_2} \Longrightarrow 2x_1 = 2x_2 \Longrightarrow x_1 = x_2; \tag{10}$
then it follows that
$(\cos y_1, \sin y_1) = (\cos y_2, \sin y_2) \Longrightarrow \cos y_1 = \cos y_2, \; \sin y_1 = \sin y_2; \tag{11}$
the only way this may bind with $0 < y_1, y_2 < 2\pi$ is if
$y_1 = y_2, \tag{12}$
thus establishing the injectivity of $f(x, y)$ on the set where
$0 < y_1, y_2 < 2\pi$.