As the others have pointed out, one fundamental use of ordered basis is to specify coordinates. Often, when we say something like $v=(1,2,3)$, we have already assumed that we are talking about coordinates w.r.t. an ordered basis: the canonical basis. If the order is not known, all we know is that $v$ has three coordinates $1,2,3$, but which one is the $x$-coordinate and which ones are $y$ and $z$ would be unknown to us, and hence we cannot be sure where exactly the point $v$ is.
Another purpose of ordering a basis is to make the matrix representation of a linear operator simpler. For instance, consider $f:\mathbb{R}^5\to\mathbb{R}^5$, where the matrix representation of $f$ w.r.t. the canonical basis $A=\{e_1,\ldots,e_5\}$ is given by
$$
[f]_A^A=\begin{pmatrix}
3&0&4&0&2\\
5&4&0&0&4\\
0&0&2&0&1\\
2&0&5&1&3\\
0&0&0&0&1
\end{pmatrix}.
$$
Can you tell me the value of $\det f$? For some, the answer can be obtained using only mental calculation, but for the others, the answer is not that easy to obtain. However, if we reorder the basis as $B=\{e_4,e_2,e_1,e_3,e_5\}$, the answer will become utterly obvious:
$$
[f]_B^B=\begin{pmatrix}
1&0&2&5&3\\
0&4&5&0&4\\
0&0&3&4&2\\
0&0&0&2&1\\
0&0&0&0&1
\end{pmatrix}.
$$
Admittedly, this example is a bit contrived, but the reordering of bases does sometimes help simplifying the structure of a matrix. For instance, in my answer to a recent question, I had used this trick to make the matrix representation of a certain linear operator block upper triangular, so that I could write down the determinant of this operator immediately.