$F$ is a field. $a$ is in some extention $E$ of $F$ and $a$ is transcendental over $F$. I think that $F(a)$, the smallest subfield of E that contains both $F$ and $a$ can be constructed in such a way.
Let $A=\{f(a)|f(x) \in F[x]\}$. If we view E as a ring, it can be verified that A is a subring of E. It can also be verified that A is an integral domain(since E is a field). As an integral domain, A can be extended to it's field of fractions, say B. Since B obviously contains $F$ and $a$, and that $F(a)$ is smallest, we claim that $B=F(a)$. This a a fact noticed by me, I wonder if it's correct.
edit: $a$ doesn't need to be transcendental over $F$.