Denote the evaluation map at $v$ by $\bar{v}$. Then the map $\tau v=\bar{v}$ from $V\to V^{\ast\ast}$ is indeed an injective linear transformation. Linearity is easy. Now suppose $v\in\ker(\tau)$. Then
$$
\begin{align*}
\tau v=0 &\implies \bar{v}=0\\
&\implies \bar{v}(f)=0\quad\forall f\in V^\ast\\
&\implies f(v)=0\quad\forall f\in V^\ast\\
&\implies v=0
\end{align*}
$$
since $v\in V$ is zero iff $f(v)=0$ for all linear functionals on $V$. Thus $\ker(\tau)=\{0\}$, so $\tau$ is injective.
To see it is an isomorphism, it is useful to recall the fact that
$$
\dim(V)\leq\dim(V^\ast)
$$
with equality holding iff $V$ is finite dimensional, so applying this twice you find
$$
\dim(V)=\dim(V^\ast)=\dim(V^{\ast\ast})
$$
so $\tau$ is an injective transformation between vector spaces of equal dimension, hence and isomorphism by rank-nullity.