For $n \geq 1$ observe that we can form the push out diagram
$ \require{AMScd}\begin{CD}
S^n @>{\pi}>> \mathbb{R}\mathbb{P}^n\\
@VVV @VVV \\
D^{n+1} @>{}>> \mathbb{R}\mathbb{P}^{n+1}
\end{CD}$
where $\pi \colon S^n \rightarrow \mathbb{R}\mathbb{P}^n$ is the projection if we consider $\mathbb{R}\mathbb{P}^n$ as a sphere with identified antipodal points and the left vertical map is the inclusion of a sphere in a disk as boundary.
This let us define inductively a CW complex structure on $\mathbb{R}\mathbb{P}^n$.
EDIT: I will explain better my answer.
First let us start with the CW complex structure on $D^n$: as Prototank explained you have such a structure on $S^1$ by taking two points and gluing two segments (which are just copies of $D^1$) to these the endpoints. You you consider the usual embedding of $S^1$ in $\mathbb{R}^2$ you can take the two points to be $(1,0)$ and $(-1,0)$ and the two segments to be the upper and lower emispheres. Notice that these two points can be identified with $S^0$ which is the intersection of $S^1$ with the line $y=0$.
Now we can use this top construct a CW complex on $S^2$: consider $S^1 \subset S^2$ the equator for $z=0$, we want this to be the $1$-skeleton of the sphere. So we attach to this two disks $D^2$ by gluing their boundaries $\partial D^2=S^1$ along the copy of $S^1$ we start with. In this way clearly we get a sphere $S^2$ as we wanted.
Now you can inductively construct a CW complex structure on $S^n$ for any $n$: you just attach two $n$-disks $D^n$ along their boundaries to a copy of $S^{n-1}$ which by induction has already a CW-structure. You will see that the $S^{n-1}$ is just the equator obtained intersecting the $n$-sphere in $\mathbb{R}^{n+1}$ with the plane $x_{n+1}=0$ and the two disks form the two hemispheres.
Now we want to induce a CW structure on $\mathbb{R}\mathbb{P}^n$: by definition this space is just the sphere $S^n$ modulo the identification of the antipodal points. We can reformulate this as follows: we can define on $S^n$ an action of $C_2$ (the $2$-cyclic group) by sending an element $x$ to its antipodal $-x$. The key property of this action is that it respects the CW complex structure we defined above on the sphere. Consider the case of $S^1$: this has two $0$-cells given by the points $(1,0)$ and $(-1,0)$ and two $1$-cells given by the two hemispheres. The action we defined maps one of the $1$-cells to the other, moreover it maps the interior of the $1$-cell to the interior of the other cell. Similarly it maps the two points to each other (since they are points the statement about the interior is trivial). You can see that this property holds for every $S^n$ for its $k$-cells for $0 \leq k \leq n$.
Now there is a important theorem that says in this situation the quotient $S^n/C_2=\mathbb{R}\mathbb{P}^n$ inherits a CW structure from the original space in which a $k$-cell is given by the $k$-cells identified by the group action. This is the CW complex structure we are interested on the projective space.
So we have established that the CW-structure $\mathbb{R}\mathbb{P}^n$ is the quotient of the one on $S^n$: the latter consists of attaching two $n$-disks to a copy of $S^{n-1}$. Now when we identify the antipodal points the two hemispheres become the same $n$-cell. What about the equator? This is a copy of $S^{n-1}$ in which we are identifying the antipodal point: by definition this is just $\mathbb{R}\mathbb{P}^{n-1}$. Therefore we can describe the CW-structure on $\mathbb{R}\mathbb{P}^n$ alternatively as gluing an $n$-cell on a copy of $\mathbb{R}\mathbb{P}^{n-1}$.
This is what the pushout I wrote was refering to: the pushout is a categorical construction (see here https://en.wikipedia.org/wiki/Pushout_(category_theory)) which in the category of topological spaces reduces to attaching the bottom left and upper right corners along the maps included in the diagram. The result of the gluing is the space in the lower right corner. In our case we are attaching the $n$-disk to $\mathbb{R}\mathbb{P}^n$ to get $\mathbb{R}\mathbb{P}^{n+1}$ as I described above.