If $A$ is an $(m,n)$ matrix, then Since $K^{(m,n)}\operatorname{vec}(A)=\operatorname{vec}(A^T)$.
Consider the $(n,m)$ matrix $B$. Then $K^{(n,m)}\operatorname{vec}(B)=\operatorname{vec}(B^T)$, hence $K^{(n,m)}K^{(m,n)}\operatorname{vec}(A)=\operatorname{vec}(A)$, i.e. $K^{(n,m)}K^{(m,n)}=1$ and similarly $K^{(m,n)}K^{(n,m)}=1$, i.e. $K^{(n,m)}$ and $K^{(m,n)}$ are inversers of each other, especially are invertible.
Note that
$$\langle\operatorname{vec}(A),\operatorname{vec}(B^T)\rangle=\operatorname{vec}(A)^T\operatorname{vec}(B)=\operatorname{tr}(AB)=\operatorname{tr}(A^TB^T),$$
hence
$$\langle\operatorname{vec}(A), K^{(n,m)}\operatorname{vec}(B)\rangle
=\langle K^{(m,n)}\operatorname{vec}(A),\operatorname{vec}(B)\rangle,$$
i.e. $K^{(n,m)}$ and $K^{(m,n)}$ are also transposes of each other, i.e.
$$(K^{(n,m)})^{-1}=K^{(m,n)}=(K^{(n,m)})^T.$$