Let $a<c<b$. The function $f$ is integrable over $]a,b[ \iff f$ is integrable over $]a,c[$ and $]c,b[$. We get: $\int_a^bf=\int_a^cf+\int_c^bf $
In the proof of this theorem ($\Leftarrow$), we take an arbitrary partition $\pi_L$ of $]a,c[$ and a partition $\pi_R$ of $]c,b[$. Then we consider the partition $\pi := \pi_L \cup \pi_R$ of $]a,b[$.
We get that $s_{\pi_L}+s_{\pi_R} = s_\pi \le \underline{\int_a^b} f$. Why does this equality hold here?