Edit: My proof is not valid, as I forgot about $\mathtt{XOR}$. Nevertheless, I will leave it here, it still might be useful for somebody.
Edit 2: As I don't know how to simply fix this issue, I will give a short informal argument based on information theory: with $x_i$ being used only once, we have only 1 bit (the output of some sub-expression) to convey 2 bits of information:
- whether the previous comparison succeed,
- whether we are comparing to $0$ or to $1$.
It is possible for $n = 2$, because we don't need to propagate the "previous comparisons succeeded" bit (there is no previous comparisons). If only we could use every $x_i$ twice, it would be possible for any $n$, because we could implement (0).
This is impossible. As different indices/bits of input numbers are treated independently, WLOG we can assume that all the input $x_i \in \{0,1\}$. So we have a sequence $x_i$ and want to construct a logical expression which is equivalent to
$$\left(\forall i.\ x_i = 1\right) \lor \left(\forall i.\ x_i = 0\right), \tag{0}$$
such that every $x_i$ is used at most once. It is doable for $n \leq 1$, but impossible otherwise, i.e. for $n > 1$. Let's assume that a Boolean function $f(x_0,\ldots)$ uses $x_0$ only once, then $f$ is increasing in $x_i$ or $f$ is decreasing in $x$, more formally
$$\forall (x_i)\subset\{0,1\}^n.\ f(0,x_1,\ldots) \leq f(1,x_1,\ldots), \tag{1}$$
or
$$\forall (x_i)\subset\{0,1\}^n.\ f(0,x_1,\ldots) \geq f(1,x_1,\ldots). \tag{2}$$
The reason being, operators $\lor$ and $\land$ are monotonic and if $x_0$ is used only once, then there is a constant number $k_0$ of negations along the way. $\mathtt{NAND}$ is just $\mathtt{NOT} \circ \mathtt{AND}$, and if $k_0$ is even then (1), and for $k_0$ odd we have (2).
By symmetry, it is the same for $x_i$ for any $i$. However, the desired operation $equiv(x_0,x_1,x_2)$ does not fulfill (1) or (2), e.g.
\begin{align}
equiv(0,0) &= 1 \\
equiv(1,0) &= 0 \\
equiv(0,1) &= 0 \\
equiv(1,1) &= 1
\end{align}
Concluding, $equiv(x_0,\ldots)$ for $n > 1$ does not fulfill (1) or (2) and thus is not expressible in terms of $\lor, \land,\neg$ with variables being used only once.
I hope it answers your question ;-)