When attempting to solve equations using the Lambert $W$ function, one usually has to exploit the fact that different manipulations affect the "coefficient" in front of $e$ and the exponent above $e$ differently.
In this case, you have $x^2$ in the exponent, so you want that in the coefficient as well. We can try squaring our equation and see where that gets us:
$$
x^2e^{2x^2} = 1
$$
OK. This squared the coefficient but doubled the exponent. So now we have $x^2$ both places. However, the exponent is $2x^2$ instead of $x^2$. So, we multiply our equaiton by $2$ to get
$$
2x^2e^{2x^2} = 2
$$
Now we can apply the Lambert $W$ function to get
$$
2x^2 = W(2)\\
x = \sqrt{W(2)/2}
$$