Note that every element in $A\in\operatorname{conv}(A_1,\dots,A_k)$ can be written as $A = \sum_{i=1}^n \lambda_i A_i$, where $\lambda_i\in [0,1]$ and $\sum_{i=1} \lambda_i = 1$. In particular we also have $b = \sum_{i=1} \lambda_i b$. Consequently we obtain the following inequality
\begin{align}
\|Ax - b\| &= \Big\|\sum_{i=1}^n \lambda_i A_i x -\sum_{i=1}^n \lambda_i b\Big\|
=\Big\|\sum_{i=1}^n \lambda_i(A_ix-b)\Big\| \leq \sum_{i=1}^n \lambda_i\|A_i x-b\|\\
&\leq \sum_{i=1}^n \lambda_i \max_{i=1,\dots,k}\|A_i x-b\| = \max_{i=1,\dots,k}\|A_i x-b\|
\end{align}
for arbitrary $x\in \mathbb{R}^n$ and $b\in \mathbb{R}^m$.
One immediate consequence is
$$
\sup_{A\in\operatorname{conv}(A_1,\dots,A_k)} \|Ax - b\| \leq \max_{i=1,\dots,k}\|A_i x-b\|.
$$
On the other hand since every $A_i \in \operatorname{conv}(A_1,\dots,A_k)$ we also have
$$
\sup_{A\in\operatorname{conv}(A_1,\dots,A_k)} \|Ax - b\| \geq \max_{i=1,\dots,k}\|A_i x-b\|.
$$
Hence, we have equality. Clearly this won't change if we minimize over $x\in \mathbb{R}^n$.
So this has nothing to do with the minimization problem. In fact this is the key essence of the simplex algorithm.