In a review of H.R. Pitt's Integration, Measure and Probability, Sir John Kingman wrote,
The author is often careless about details, asserting for instance (on page 105) that a function continuous on the rationals has a continuous extension to the reals.
Using the properties of Cauchy sequences and completeness of $\mathbb R$, I can prove that if $f:\mathbb Q\to\mathbb R$ is uniformly continuous, then there exists a continuous function $g:\mathbb R\to\mathbb R$ such that $f=g$ on $\mathbb Q$.
It follows that any inextensible $f$ cannot be uniformly continuous on $\mathbb Q$. However, I am unable to come up with a concrete example.