Suppose that $R(x)$ is a rational function of $x$. Then
$$
\begin{align}
\frac{\mathrm{d}}{\mathrm{d}x}\left(R(x)\,e^{-1/x^2}\right)
&=\left(R'(x)+\frac{2R(x)}{x^3}\right)e^{-1/x^2}
\end{align}
$$
where $R'(x)+\frac{2R(x)}{x^3}$ is another rational function of $x$.
Inductively, we have that there is some rational $R(x)$,
$$
\frac{\mathrm{d}^k}{\mathrm{d}x^k}e^{-1/x^2}=R(x)\,e^{-1/x^2}\tag{1}
$$
Since $R(1/x)$ is also a rational function of $x$, there is an $n$ so that
$$
\lim_{x\to\infty}\frac{R(1/x)}{x^{2n}}=0
$$
Furthermore,
$$
\begin{align}
\lim_{x\to+\infty}x^ne^{-x}
&=\lim_{x\to+\infty}\frac{x^n}{e^x}\\
&=\lim_{x\to+\infty}\frac{n!}{e^x}&&\text{applying L'Hospital $n$ times}\\[5pt]
&=0
\end{align}
$$
Now we need to show that
$$
\begin{align}
\lim_{x\to0}R(x)\,e^{-1/x^2}
&=\lim_{u\to\infty}R(1/u)\,e^{-u^2}\\
&=\lim_{u\to\infty}\frac{R(1/u)}{u^{2n}}\,\lim_{u\to\infty}u^{2n}e^{-u^2}\\
&=\lim_{u\to\infty}\frac{R(1/u)}{u^{2n}}\,\lim_{v\to+\infty}v^ne^{-v}\\[7pt]
&=0\cdot0\tag{2}
\end{align}
$$
Combining $(1)$ and $(2)$ yields
$$
\lim_{x\to0}\frac{\mathrm{d}^k}{\mathrm{d}x^k}e^{-1/x^2}=0\tag{3}
$$