There's no "best exponent", because you can always get better and better exponents, but you can use continued fractions to do this systematically. With continued fractions, we will write $x$ in the form
$$
x = a_0 + \cfrac1{a_1 + \cfrac1{a_2 + \cfrac1{a_3 + \cfrac1{a_4 + \dots}}}}.
$$
where $a_0, a_1, a_2, a_3, a_4, \dots$ is an infinite sequence of natural numbers.
We can truncate this sequence at any point, getting upper or lower bounds depending on where we stop. (If you stop at an even $a_k$, you get a lower bound; if you stop at an odd $a_k$, you get an upper bound.)
We compute the sequence iteratively: $a_0$ is $\lfloor x\rfloor$ (the greatest integer less than $x$) and to find $a_1$ onward you just replace $x$ by $\frac{1}{x - a_0}$.
All this is abstract and general, so here is how it will go in your example.
Let $x = \log_5(3)$. Then we can estimate that $0 < x < 1$ (because $5^0 < 3 < 5^1$) so $a_0 = \lfloor \log_5(3)\rfloor = 0$, and we will keep going with $\frac1{\log_5(3)} = \log_3(5)$.
We can estimate that $1 < \log_3(5) < 2$, because $3^1 < 5 < 3^2$, so $a_1 = \lfloor \log_3(5)\rfloor = 1$, and we will keep going with $\frac{1}{\log_3(5)-1} = \frac1{\log_3(5/3)} = \log_{5/3}(3)$.
We can estimate that $2 < \log_{5/3}(3) < 3$, because $(\frac53)^2 < 3 < (\frac53)^3$ (this expands to $25 < 27$ but $81 < 125$), so $a_2 = \lfloor \log_{5/3}(3) \rfloor = 2$, and we will keep going with $\frac1{\log_{5/3}(3) - 2} = \frac1{\log_{5/3}(27/25)} = \log_{27/25}(\frac53)$.
We could estimate that $6 < \log_{27/25}(\frac53) < 7$, because $(\frac{27}{25})^6 < \frac53 < (\frac{27}{25})^7$, but this has gotten tricky to check: it involves checking that $3^{19} < 5^{13}$ but $3^{22} > 5^{15}$. This gives us $a_3 = 6$, but maybe we'd better quit while we're ahead, or get a computer.
At this point, our best lower bound is
$$
a_0 + \cfrac1{a_1 + \cfrac1{a_2}} = 0 + \cfrac1{1 + \cfrac12} = \frac23
$$
and our best upper bound is
$$
a_0 + \cfrac1{a_1 + \cfrac1{a_2 + \cfrac1{a_3}}} = 0 + \cfrac1{1 + \cfrac1{2 + \cfrac16}} = \frac{13}{19}.
$$