I just consider two $\mathbb{R}$-linear spaces $V$ and $W$ in order to simplify the notation, but this works in general.
Let $\{e_1,...,e_n \}$ be a basis of $V$ and let $\{f_1,...,f_m\}$ be a basis of $W$.
For any $i \in \{1,...,n \}$ and any $j \in \{1,...,m \}$, let $F_{i,j}$ be the element of $L(V,W;\mathbb{R})$ such that $$F_{i,j}(v,w)=v_iw_j$$ for every $(v,w) \in V\times W$, being $v_i$ the $i$-th component of $v$ (with respect to the given basis) and being $w_j$ the $j$-th component of $w$ (with respect to the given basis).
Then $\{F_{i,j}: i \in \{1,...,n \}, j \in \{1,...,m \}\}$ is a basis of $L(V,W;\mathbb{R})$.
For the linear independence, observe that, if $\lambda_{1,1},\lambda_{1,2},...\lambda_{n,m}$ are real numbers such that $\sum_{i,j}\lambda_{i,j} F_{i,j}$ is the null element of $L(V,W,\mathbb{R})$, then $0=\sum_{i,j}\lambda_{i,j}F_{i,j}(e_{i'},f_{j'})=\lambda_{i',j'}$ for every $i' \in \{1,...,n\}$ and every $j' \in \{1,...,m\}$.
For the generation, observe that, for every $F\in L(V,W,\mathbb{R})$, it is the case that:
\begin{aligned}
F(v,w)&=F(v_1e_1+...+v_ne_n,w_1f_1+...+w_mf_m) \\
&=F(e_1,f_1)v_1w_1+...+F(e_n,f_m)v_nw_m\\
&=F(e_1,f_1)F_{1,1}(v,w)+...+F(e_n,f_m)F_{n,m}(v,w)
\end{aligned}
for every $(v,w)\in V\times W$. Hence $F=F(e_1,f_1)F_{1,1}+...+F(e_n,f_m)F_{n,m}$.