It's a charming problem :
Let $a,b,c>0$ such that $a+b+c=1$ then we have : $$\frac{a}{\exp(a+b)}+\frac{b}{\exp(b+c)}+\frac{c}{\exp(c+a)}\leq \exp\Big(\frac{-2}{3}\Big)$$
I know the identity :
Let $a,b,c>0$ such that $a+b+c=1$ then we have : $$\frac{a}{a+b}+\frac{b}{b+c}+\frac{c}{c+a}=1.5$$
But I think it's not relevant here .
I try also majorization with the inequality :
Let $a\geq b\geq c>0$ such that $a+b+c=1$ then we have :
$$\exp\Big(\frac{-2}{3}\Big)a\geq \frac{a}{\exp(a+b)}$$
Second line of the majorization :
$$\exp\Big(\frac{-2}{3}\Big)^2ab\geq \frac{a}{\exp(a+b)}\frac{b}{\exp(b+c)}$$
Third line of the majorization :
$$\exp\Big(\frac{-2}{3}\Big)^3abc\geq \frac{a}{\exp(a+b)}\frac{b}{\exp(b+c)}\frac{c}{\exp(c+a)}$$
The lines are easy to check with the condition remains to apply Karamata's inequality and we are done . Unfortunately the second line fails .
My question : Have you a proof ?
Thanks a lot for sharing your time and knowledge .