We have that
$$
{{\left( \matrix{ n \cr k \cr} \right)} \over {\left( \matrix{ 2n - 1 \cr k \cr} \right)}}
= {{n^{\,\underline {\,k\,} } } \over {\left( {2n - 1} \right)^{\,\underline {\,k\,} } }}
= {{\left( { - 1} \right)^{\,k} \left( { - n} \right)^{\,\overline {\,k} } } \over {\left( { - 1} \right)^{\,k} \left( { - 2n + 1} \right)^{\,\overline {\,k} } }}
= {{\left( { - n} \right)^{\,\overline {\,k} } } \over {\left( { - 2n + 1} \right)^{\,\overline {\,k} } }}
$$
where $x^{\,\underline {\,k\,} } ,\quad x^{\,\overline {\,k\,} } $ represent respectively the Falling and Rising Factorial.
Therefore
$$
S(x,n)=\sum\limits_{0\, \le \,k\,\left( { \le \,n} \right)} {{{\left( \matrix{ n \cr k \cr} \right)}
\over {\left( \matrix{ 2n - 1 \cr k \cr} \right)}}x^{\,k} }
= \sum\limits_{0\, \le \,k\,\left( { \le \,n} \right)}
{{{1^{\,\overline {\,k} } \left( { - n} \right)^{\,\overline {\,k} } }
\over {\left( { - 2n + 1} \right)^{\,\overline {\,k} } }}{{x^{\,k} } \over {k!}}}
= {}_{2}F_{\,1} \left( {\left. {\matrix{ {1,\,\, - n} \cr { - 2n + 1} \cr } \,} \right|\;x} \right)
$$
But the Hypergeometric with the parameters shown is not easy to handle.
Instead of working in finding equivalent forms for the hypergeometric, we change the approach and rewrite
the starting sum as
$$
\eqalign{
& S(x,n) = \sum\limits_{0\, \le \,k\, \le \,n}
{{{\left( \matrix{ n \cr k \cr} \right)} \over {\left( \matrix{ 2n - 1 \cr k \cr} \right)}}x^{\,k} }
\quad \left| {\;1 \le n} \right.\quad = \cr
& = \sum\limits_{0\, \le \,k\, \le \,n}
{{{\left( \matrix{ n \cr n - k \cr} \right)} \over {\left( \matrix{ 2n - 1 \cr n - 1 + n - k \cr} \right)}}
x^{\,n - \left( {n - k} \right)} }
= x^{\,n} \sum\limits_{0\, \le \,k\, \le \,n} {{{\left( \matrix{ n \cr k \cr} \right)}
\over {\left( \matrix{ 2n - 1 \cr n - 1 + k \cr} \right)}}x^{ - \,k} } \cr
& = x^{\,n} \sum\limits_{0\, \le \,k\, \le \,n} {{{n^{\,\underline {\,k\,} } \left( {n - 1 + k} \right)!}
\over {k!\left( {2n - 1} \right)^{\,\underline {\,n - 1 + k\,} } }}x^{ - \,k} }
= x^{\,n} \sum\limits_{0\, \le \,k\, \le \,n} {{{n^{\,\underline {\,k\,} } \left( {n - 1 + k} \right)!}
\over {k!\left( {2n - 1} \right)^{\,\underline {\,n - 1\,} } n^{\,\underline {\,k\,} } }}x^{ - \,k} } = \cr
& = {{x^{\,n} } \over {\left( {2n - 1} \right)^{\,\underline {\,n - 1\,} } }}\sum\limits_{0\, \le \,k\, \le \,n}
{{{\left( {n - 1 + k} \right)!} \over {k!}}x^{ - \,k} } = {{\left( {n - 1} \right)!x^{\,n} }
\over {\left( {2n - 1} \right)^{\,\underline {\,n - 1\,} } }}
\sum\limits_{0\, \le \,k\, \le \,n} {\left( \matrix{ n - 1 + k \cr k \cr} \right)x^{ - \,k} } = \cr
& = {{x^{\,n} } \over {\left( \matrix{ 2n - 1 \cr n - 1 \cr} \right)}}
\sum\limits_{0\, \le \,k\, \le \,n}
{\left( \matrix{ n - 1 + k \cr k \cr} \right)x^{ - \,k} } \cr}
$$
So
$$
\eqalign{
& S(1,n)
= {1 \over {\left( \matrix{ 2n - 1 \cr n - 1 \cr} \right)}}\sum\limits_{0\, \le \,k\, \le \,n}
{\left( \matrix{ n - 1 + k \cr k \cr} \right)} = \cr
& = {1 \over {\left( \matrix{ 2n - 1 \cr n - 1 \cr} \right)}}
\sum\limits_{\left( {0\, \le } \right)\,k\,\left( { \le \,n} \right)}
{\left( \matrix{ n - k \cr n - k \cr} \right)\left( \matrix{ n - 1 + k \cr k \cr} \right)} = \cr
& = {{\left( \matrix{ 2n \cr n \cr} \right)} \over {\left( \matrix{ 2n - 1 \cr n \cr} \right)}}
= {{\left( {2n} \right)!n!\left( {n - 1} \right)!} \over {n!n!\left( {2n - 1} \right)!}} = 2 \cr}
$$