Typoically, to show that some argument is invalid, we show a way of making the premises true and the conclusion false. That won;t work here, since axioms 2 and 2 are truth-functional tautologies.
So, to show that we cannot derive axioms 2 and 3 from axiom 1 plus Modus Ponens, we need to come up with some non-standard interpretation of the symbols and operators involved.
Here is one: Suppose that the propositional variables can take on the values of $0$ and $1$, and that the operators work on those values as specified by the following tables:
\begin{array}{c|c}
A&\neg A\\
\hline
0&0\\
1&0\\
\end{array}
\begin{array}{cc|c}
A&B&A \to B\\
\hline
0&0&0\\
0&1&1\\
1&0&0\\
1&1&0\\
\end{array}
OK, now let's put axioms 1 and 3 on a table:
\begin{array}{cc|ccc|ccc}
A&B&A & \to & (B \to A)&(\neg B \to \neg A) & \to & (A \to B)\\
\hline
0&0&&0&0&0&0&0\\
0&1&&0&0&0&1&1\\
1&0&&0&1&0&0&0\\
1&1&&0&0&0&0&0\\
\end{array}
Let's call a statement that always evaluates to $0$ a $0$-tautology. Note that axiom-1 is a $0$-tautology, but axiom 3 is not. But now notice that, using Modus Ponens, if $A \to B$ has value $0$, and $A$ has value $0$, then $B$ has to have value $0$ as well. In other words, from $0$-tautologies we can only infer further $0$-tautologies; we can't infer something that is not a $0$-tautology.
So, axiom 3 cannot be derived from axiom 1 and Modus Ponens.
Can you do something similar for axiom 2? You may have to move to a $3$-value system ....