For any tetrahedron $\mathcal{T}$, let $V$ be its volume, $\Delta_i$ and $h_i$ be its face areas and corresponding altitudes. Since
$$\color{red}{3} V = \Delta_1 h_1 = \Delta_2 h_2 = \Delta_3 h_3 = \Delta_4 h_4$$
The expression we want to minimize equals to
$$f(\mathcal{T}) \stackrel{def}
= \sum_{1 \le i < j \le 4} \Delta_i h_j
= 3V \sum_{1 \le i < j \le 4} \frac{\Delta_i}{\Delta_j}
= 3V\left(\frac{\Delta_1 + \Delta_2 + \Delta_3}{\Delta_4}
+ \frac{\Delta_1 + \Delta_2}{\Delta_3} + \frac{\Delta_1}{\Delta_2}\right)
$$
The task at hand is to minimize $f(\mathcal{T})$ subject to the constraint the four numbers $\Delta_1, \Delta_2, \Delta_3, \Delta_3$ can be realized as the face area of a tetrahedron $\mathcal{T}$ with $V = 5$.
In general, given four positive numbers $A_1, A_2, A_3, A_4$, it can be realized as the face area of a non-degenerate tetrahedron when and only when they satisfy following 4 inequalities (for a proof, see this):
$$\begin{cases}
A_1 + A_2 + A_3 &> A_4\\
A_2 + A_3 + A_4 &> A_1\\
A_3 + A_4 + A_1 &> A_2\\
A_4 + A_1 + A_2 &> A_3
\end{cases}\tag{*1}$$
This implies
$$f(\mathcal{T}) > 3V \left(\frac{\Delta_1 + \Delta_2 + \Delta_3}{\Delta_4}\right) > 3V = 15\tag{*2}$$
This leads to $$\inf\limits_{V(\mathcal{T}) = 5}f(\mathcal{T}) \ge 15$$
For any $\epsilon \in (0,1)$, consider the four numbers $(A_1,A_2,A_3,A_4) = (\epsilon^2,\epsilon,1,1)$. It is easy to see they satisfies inequalities $(*1)$ and hence can be realized by as the face area of some non-degenerate tetrahedron.
By suitable scaling, we can find a tetrahedron $\mathcal{T}_{\epsilon}$
with volume $5$ and
$$\Delta_1 : \Delta_2 : \Delta_3 : \Delta_4 = A_1 : A_2 : A_3 : A_4 = \epsilon^2 : \epsilon : 1 : 1$$
For such a tetrahedron, we have
$$f(\mathcal{T}_\epsilon) = 15\left(\frac{\epsilon^2 + \epsilon +1}{1} + \frac{\epsilon^2 + \epsilon}{1} + \frac{\epsilon^2}{\epsilon}\right) = 15(1+3\epsilon+\epsilon^2)$$
Form this, we can deduce
$$\inf_{V(\mathcal{T}) = 5} f(\mathcal{T}) \le \lim_{\epsilon\to 0} f(\mathcal{T}_\epsilon) = 15$$
As a result, the infimum of $\sum\limits_{1 \le i < \le j} \Delta_i h_i$ is $15$. Since
the inequality in $(*2)$ is always strict, the minimum of the expression at hand doesn't exist.