Note that the matrix
$$
A = \pmatrix{1&i\\i&-1}
$$
is symmetric but fails to be diagonalizable (since $A^2 = 0$). It follows that
$$
M = \pmatrix{0&1\\-1&0} \otimes A = \pmatrix{0&0&1&i\\0&0&i&-1\\-1&-i&0&0\\-i&1&0&0}
$$
is skew-symmetric and also fails to be diagonalizable.
Notable facts, Horn and Johnson's Matrix Analysis, second edition.
Corollary 4.4.19: Let $A \in M_n$ be skew-symmetric. Then $r = \operatorname{rank}(A)$ is even, the non-zero singular values of $A$ occurs in pairs $\sigma_1 = \sigma_2 = s_1 \geq \sigma_3 = \sigma_4 = s_2 \geq \cdots \geq \sigma_{r-1} = \sigma_r = s_{r/2} \geq 0$, and $A$ is unitarily congruent to
$$
0_{n-r} \oplus \pmatrix{0&s_1\\-s_1 & 0} \oplus \cdots \oplus \pmatrix{0&s_{r/2}\\-s_{r/2} & 0}.
$$
and fact 2:
4.4.P34: Although a symmetric complex matrix can have any given Jordan canonical form (4.4.24), the Jordan canonical form of a skew-symmetric complex matrix has a special form. It consists of only the following three types of direct summands: (a) pairs of the form $J_k(\lambda) \oplus J_k(-\lambda)$, in which $\lambda \neq 0$; (b) pairs of the form $J_k(0) \oplus J_k(0)$, in which k is even; and (c) $J_k(0)$, in which k is odd.