Heavy sketch for the first one, the rest is left for you.
$$\operatorname{Dom}(R\cup S)=\operatorname{Dom}(R)\cup\operatorname{Dom}(S).$$
Since these are sets, use a standard set-equality proof:
Let $a\in \operatorname{Dom}(R\cup S)$. Then, there is some $b$ such that $(a,b)\in R\cup S$. By the definition of union, $(a,b)\in R$ or $(a,b)\in S$. Therefore, $a\in\operatorname{Dom}(R)$ or $a\in\operatorname{Dom}(S)$ by cases.
Let $a\in\operatorname{Dom}(R)\cup\operatorname{Dom}(S)$. Then $a\in\operatorname{Dom}(R)$ or $a\in\operatorname{Dom}(S)$. Wlog, we'll consider the first case. Then there is some $b$ such that $(a,b)\in R$. Since $R\subseteq R\cup S$, $(a,b)\in R\cup S$. Hence $a\in \operatorname{Dom}(R\cup S)$.