They don't say it, but the relation is on ordered pairs of naturals, not on naturals. Once you have proven that $\sim$di is an equivalence relation on $X \times X$ it separates the pairs in $X \times X$ into equivalence classes. In part B you are expected to show that every pair in $X \times X$ is equivalent to exactly one of the given pairs. This also requires showing that no two of the given pairs are equivalent.
For a similar but simpler problem, let our set be $\Bbb Z$, the integers, and the relation being equivalence $\bmod 5$. Part A would ask us to show that this is an equivalence relation. Part B might ask to show that $\{0,1,2,3,4\}$ is a set of representatives, so every integer is equivalent to exactly one of these. It could also ask us to show that $\{-73,41,9,-15,1004\}$ is a set of representatives. This is also a set of representatives, but it is harder to keep track of.