The integrand is continuous and, therefore, Riemann integrable on $[0,k]$ for every $k \in \mathbb{N}$. Riemann and Lebesgue integrals coincide on finite intervals, whence, with $f(x) = e^{-x}x^n$ we have
$$\int_{[0,\infty)}f_k =\int_{[0,\infty)}f\chi_{[0,k]} = \int_0^k f(x) \, dx$$
Since $\lim_{x \to \infty} f(x)x^{2} = 0$, there exists $x_0 > 0$ such that $f(x) < x^{-2}$ for all $x \geqslant x_0$. We also have (using Riemann integrals), $\int_{x_0}^k f(x) \, dx \leqslant \int_{x_o}^k x^{-2} \, dx = 1/x_0 - 1/k < 1/x_0$, and, consequently, the following conditions are met:
(1) The sequence $(f_k)$ is a monotone increasing sequence of nonnegative, measureable functions converging to $f$; and (2) the integrals $\int_{[0,\infty)} f_k$ are bounded for all $k \in \mathbb{N}$.
When both of these conditions hold, the monotone convergence theorem guarantees that $f$ is Lebesgue integrable on $[0,\infty)$.