For the first question, $5^3=5^2\cdot 5$. But $5^2\equiv 3$.
For the second, unless there is a typo, I suspect the question has shape find the remainder when $a^{2^{68}}$ is divided by $19$. For the calculation, if $a$ is not divisible by $19$, we want to use the fact that $a^{18}\equiv 1\pmod{19}$. So we want to begin by calculating the remainder when $2^{68}$ is divided by $18$. Also, it looks as though the thing you call $68\ast 3$ is meant to be $18\ast 3$.
If the problem is to find the ramainder when $2^{68}$ is divided by $19$, note that by Fermat's Theorem we have $2^{18}\equiv 1\pmod{19}$. Note that $68=3\cdot 18+14$. So $2^{68}=2^{18\cdot 3}2^{14}=(2^{18})^3\cdot 2^{14}\equiv 2^{14}\pmod{19}$.
So now we need to calculate the remainder when $2^{14}$ is divided by $19$. We have $2^{3}\equiv 8\pmod{19}$, so $2^6\equiv 64\equiv 7\pmod{19}$. It follows that $2^{12}\equiv 49\equiv 11\pmod{19}$, and therefore $2^{14}\equiv 44\equiv 6\pmod{19}$. There are a number of other ways to do the calculation.
Remark: There is a more systematic way, called the binary method for exponentiation, which I recommend you look up. All congruences are modulo $19$. We have $2^2\equiv 4$, so $2^4\equiv 16\equiv -3$, so $2^8\equiv 9$, so $2^{12}= 2^8\cdot 2^4\equiv -27\equiv 11$, so $2^{14}=2^{12}\cdot 2^2\equiv 11\cdot 4\equiv 6$.