We initially assume that both $\alpha>0$ and $\beta>0$. Then, we can write
$$\begin{align}
\int_\varepsilon^L \frac{\arctan(\alpha x)-\arctan(\beta x)}{x}\,dx&=\int_\varepsilon^L \frac{\arctan(\alpha x)}{x}\,dx-\int_\varepsilon^L \frac{\arctan(\beta x)}{x}\,dx\\\\
&=\int_{\alpha \varepsilon}^{\alpha L}\frac{\arctan(x)}{x}\,dx-\int_{\beta \varepsilon}^{\beta L}\frac{\arctan(x)}{x}\,dx\\\\
&=\int_{\alpha \varepsilon}^{\beta \varepsilon}\frac{\arctan(x)}{x}\,dx-\int_{\alpha L}^{\beta L}\frac{\arctan(x)}{x}\,dx\\\\
&=\int_\alpha^\beta \frac{\arctan(\varepsilon x)-\arctan(Lx)}{x}\,dx
\end{align}$$
Letting $\varepsilon\to 0$ and $L\to \infty$ we find that for $\alpha>0$ and $\beta>0$
$$\int_0^\infty \frac{\arctan(\alpha x)-\arctan(\beta x)}{x}\,dx=\frac\pi2 \log\left(\frac{\alpha}{\beta}\right)$$
If both $\alpha<0$ and $\beta<0$, then we have
$$\int_0^\infty \frac{\arctan(\alpha x)-\arctan(\beta x)}{x}\,dx=-\frac\pi2 \log\left(\frac{\alpha}{\beta}\right)$$
The integral diverges if $\alpha \beta<0$.