Well, if $x \le 0$ then for any $n>0$ then $\frac 1n > 0$ so $x \le 0 < \frac 1n$ and $x \not\in [\frac 1n, 1]$ for any $[\frac 1n, 1]$ and so $x \not \in \cup_n [\frac 1n, 1]$.
And if $x > 1$ then for any $n>0$ then $\frac 1n \le 1 < x$ so $x\not \in [\frac 1n, 1]$ for any $[\frac 1n, 1]$ and so $x \not \in \cup_n [\frac 1n, 1]$.
ANd if $0 < x \le 1$ then.... here's the heart..... $\frac 1x \ge 1$ and there is and $m\in \mathbb N$ so that $\frac 1x < m$ (the archimedean principal). So $0< \frac 1m < x \le 1$ so $x \in [\frac 1m, 1]$. So $x \in \cup_n [\frac 1n, 1]$.
So....... $x \in \cup_n [\frac 1n, 1] \iff 0 < x \le 1 \iff x\in (0,1]$.
So $\cup_n [\frac 1n, 1] =(0,1]$