For $K$ to be a field, you need to first state: "What is the set, what is the addition operator, and what is the multiplication operator?" Once you have these understood, you need to pass the following two tests:
- Is $K$ an abelian group under +?
- Is $K - \{0\}$ an abelian group under $\times$?
So in your specific example, the set is infinite: it's $\mathbb{R} \bmod 2\pi$, which is essentially the interval $[0, 2\pi)$. The addition and multiplication operators are simply the same ones from $\mathbb{R}$ but modulo $2\pi$.
So now apply the two tests above. Is $[0,2\pi)$ an abelian group under addition mod $2\pi$? You have to go through the requirements for abelian groups (well-defined operation, closure, associativity, existence of an identity, and inverses for all elements). You should be able to convince yourself that the answer is "yes."
Now do this again for the second requirement: is $(0,2\pi)$ an abelian group under multiplication mod $2\pi$? (Notice I changed the left bracket to a paren to indicate the exclusion of 0 here.) As others have already pointed out, the operation is not well-defined: by saying that our set is "equivalent" to the interval $(0,2\pi)$ we are grouping all multiples of $2\pi$ together into one equivalence class called $0$ (because after all, $0=2\pi =4\pi =6\pi= \cdots = -2\pi = -4\pi=\cdots$ when considered mod $2\pi$). In order for multiplication to be "well defined" it must be true that you can choose any representation of a set member and multiply it by any other set member and always get the same result. But, as Ben Blum-Smith already pointed out, this fails in our setting. So multiplication is not well-defined and we don't have an abelian group. (Once you find the operation is not well-defined, you can't even sensibly ask about the other group properties, so you stop here.)
Of course this is all very long-winded. If you are taking a test, you would immediately suspect this thing isn't a field. You don't have to find all the reasons why, just find one reason. And with some experience, you would quickly "sense" that something isn't going to work with multiplication and you would zero in on this "not well-defined" problem.