Indeed the period of this chain is $d=2$, and the classes are $\{1, 3\}$ and $\{2 \}$. Starting from state $2$ at time $n=0$, the chain will be in state $2$ at any even time $n=2p$ with probability 1; and at odd times, the chain will belong to the set $\{1, 3\}$ with probability 1.

Generally speaking, for an irreducible chain, a unique partition of the state space $S$ into $d$ sets $E_0, E_1, \dots, E_{d-1}$ can be found such that, for all $k \in \{0, 1, \dots, d-1 \}$ and for any $i \in E_k$,
$$\sum_{j \in E_{k+1}} p_{i,j} = 1,$$
where by convention $E_d = E_0$, and where $d$ is maximal. Therefore the chain moves from one class to the other at each transition, and this cyclically. In other words, the transition matrix $P$ can be written with blocks as follows:
$$
\begin{array}{c c} &
\begin{array}{c c c c c} \, E_0 \,\,\,\,& E_1 \,& E_2 & \dots & E_{d-1} \end{array}\\
\begin{array}{c} E_0\\ E_1 \\ E_2\\ \vdots\\ E_{d-1} \end{array} &
\begin{pmatrix}
0 & \mathbf{A}_0 & 0 & \cdots & 0 \\
0 & \ddots & \mathbf{A}_1 & 0 & 0\\
\vdots & \ddots & \ddots & \ddots &0\\
0 & & 0& 0& A_{d-2}\\
\mathbf{A}_{d-1}& 0 & \cdots & \cdots & 0
\end{pmatrix}
\end{array}
$$
Note that if the diagonal of the transition matrix is not zero, then the chain is acyclic, i.e. $d=1$ (The converse is not true). Moreover it can be checked that $P^d$ is block-diagonal.
In our case, the order of the states can be changed to $\{1, 3, 2\}$, so that the transition matrix $P$ has the form described above:
$$
\begin{array}{c c} &
\begin{array}{c c c} 1 & 3 & 2 \end{array}\\
\begin{array}{c} 1 \\ 3 \\ 2 \end{array} &
\begin{pmatrix}
0 & 0 & 1 \\
0 & 0 & 1 \\
\frac{1}{2} & \frac{1}{2} & 0
\end{pmatrix}
\end{array}
$$
with $E_0 = \{1, 3\}$, $E_1 = \{2\}$, $\mathbf{A_0} = \begin{pmatrix}1 \\ 1\end{pmatrix}$, $\mathbf{A_1} = \begin{pmatrix}\frac{1}{2} & \frac{1}{2}\end{pmatrix}$. Moreover, we can check that the transition matrix raised to the power $d=2$ is block-diagonal:
$$P^2 = \begin{pmatrix}
\frac{1}{2} & \frac{1}{2} & 0 \\
\frac{1}{2} & \frac{1}{2} & 0 \\
0 &0 &1
\end{pmatrix}.$$