Sometime I have trouble discerning whether an $=$ or an $\equiv$ is most appropriate. I believe that $\equiv$ is typically used when a new definition is being introduced, rather than a statement expressing a result. But even if that's essentially correct (the preceding sentence), I'm still not sure when to use which... because I have seen plenty of instances where an author introduces a function or set and uses the $=$ symbol.
Consider an example in which $\equiv$ seems appropriate. Suppose I have a sequence $(a_1,q_1,\ldots,a_n,q_n)$ with some meaning. Then I might say, "To simplify notation, let $\xi \equiv (a_1,q_1,\ldots,a_n,q_n)$," or, "To simplify notation, define $\xi \equiv (a_1,q_1,\ldots,a_n,q_n)$."
Now, consider an example in which $=$ seems appropriate. Suppose $X$, $Y$, and $Z$ are well-defined random variables of interest. Then I might say, "Let $\Psi = \{ X, Y, Z \}$ be the set of random variables in our system with...." (blah blah blah...)
Now, I do not hesitate to admit that simply because I might say those sentences above, they aren't necessarily correct. But that's why I'm asking this question. To me, it's unclear when to use $=$ and when to use $\equiv$.