Let $\Phi_{X}$ and $\Phi_{Y}$ be functions $\left(0,1\right)\to\mathbb{R}$
prescribed by $u\mapsto\inf\left\{ z\in\mathbb{R}\mid F_{X}\left(z\right)\geq u\right\} $
and $u\mapsto\inf\left\{ z\in\mathbb{R}\mid F_{Y}\left(z\right)\geq u\right\} $
respectively.
These are the so-called "inverses" of $F_X$ and $F_Y$ and it is well known that $\phi_{X}\left(U\right)\stackrel{d}{=}X$ and $\phi_{Y}\left(U\right)\stackrel{d}{=}Y$ if $U$ has uniform distribution on $(0,1)$.
Eventually have a look at this answer about that fact.
Further $X\leq_{st}Y$ implies that $\Phi_{X}\left(u\right)\leq\Phi_{Y}\left(u\right)$
for every $u\in\left(0,1\right)$ and consequently: $$f\left(\Phi_{X}\left(u\right)\right)\leq f\left(\Phi_{Y}\left(u\right)\right)\text{ for every }u\in\left(0,1\right)$$
Then we find:
$$\mathbb{E}f\left(\phi_{X}\left(U\right)\right)=\int_{0}^{1}f\left(\phi_{X}\left(u\right)\right)du\leq\int_{0}^{1}f\left(\phi_{Y}\left(u\right)\right)du=\mathbb{E}f\left(\phi_{Y}\left(U\right)\right)$$
This with $\mathbb Ef(X)=\mathbb{E}f(\phi_{X}(U)$ and $\mathbb Ef(Y)=\mathbb{E}f(\phi_{Y}(U)$ so we are ready.
This all under assumption that the expectations exist of course.