This is dealt with in Shoenfield's Mathematical Logic, Chapter 3 (especially the first section and the first exercise), though be warned that that book is terse! I don't wish here to prove the relevant theorem, but just state the definitions in order to clarify the situation. To simplify, let's assume the language has only existential quantifiers (the universal quantifier can be defined in terms of existential and negation in the usual way). I'm assuming you know the definition of atomic formula, etc., and that the background language is fixed.
Before starting, here's the idea behind the whole thing. We usually talk of tautologies only with respect to propositional languages. But there is a sense in which it can be extended to first-order languages in a natural way, so that, e.g., $Px \vee \neg Px$ or $\exists x Px \vee \neg \exists x Px$ can be said to be tautologies. The definitions below show how to accomplish that; the gist of it is that you treat existential and atomic formulas as if they were propositional variables. The quoted excerpt then is claiming that if you can derive a formula without using any logical rule that is specific to the first-order calculus, that formula is a tautology. So let us see the definitions in question.
Definition 1: A formula of the form $\exists x A$ is called an instantiantion of $A$.
Definition 2: A formula is called elementary if it is either an atomic formula or an instantiation.
Definition 3: A truth valuation is a mapping from the set of elementary formulas to the set of truth-values.
Fact 1: If $V$ is a truth valuation, it is possible to extend it to all formulas of the language in the usual way, i.e. by setting $V^*(\neg A) = T$ iff $V^*(A) = F$, etc. Call $V^*$ a boolean valuation for the language.
Definition 4: $B$ is a tautological consequence of $A_1, \dots, A_n$ if $V^*(B)=T$ for every boolean valuation $V^*$ such that $V^*(A_1)= \dots =V^*(A_n)$.
Definition 5: A formula $A$ is a tautology if it is a tautological consequence of the empty set.
So pick now your favorite first-order calculus. It will probably have rules that show to reason with the quantifiers (e.g. existential instantiation and generalization), with identity (say, substitution axioms), and with the propositional connectives (say, introduction and elimination rules, or modus ponens, or whatever). We have the following:
Theorem: If a formula is derivable from the empty set using only propositional rules, then the formula is a tautology. (Cf. Shoenfield, Chap. 3, Exercise 1)