To be clear, we’d better to distinguish two notations, $\Pr \left[ X<Y\left| Y \right. \right]$ and $\Pr \left[ X<Y \right]$. The former means the conditional probability of the event $X<Y$ given the value of $Y$. The latter means the probability of the same event where $Y$ is treated as a random variable. It is essential to understand the relation between the probability and expectation of an event $A$, that is,$\Pr \left[ A \right]=\mathbb{E}\left[ {{I}_{\left\{ A \right\}}} \right]$ where ${{I}_{\left\{ A \right\}}}$ is a indication function for an event A.
Saying that, if you mean $\mathbb{E}\left[ \Pr \left[ X<Y \right] \right]$ as the expectation of the latter notation $\mathbb{E}\left[ \Pr \left[ X<Y \right] \right]=\Pr \left[ X<Y \right]$ since $\Pr \left[ X<Y \right]$ is a non-random variable and the expectation of a non-random variable is itself. If you mean $\mathbb{E}\left[ \Pr \left[ X<Y \right] \right]$ as the expectation of the former notation, that is, $\underset{Y}{\mathop{\mathbb{E}}}\,\left[ \Pr \left[ X<Y\left| Y \right. \right] \right]$, we can calculate as follows.
$$\underset{Y}{\mathop{\mathbb{E}}}\,\left[ \Pr \left[ X<Y\left| Y \right. \right] \right]=\underset{Y}{\mathop{\mathbb{E}}}\,\left[ \underset{X}{\mathop{\mathbb{E}}}\,\left[ {{I}_{\left\{ X<Y \right\}}}\left| Y \right. \right] \right]=\mathbb{E}\left[ {{I}_{\left\{ X<Y \right\}}} \right]=\Pr \left[ X<Y \right].$$
After all, $\mathbb{E}\left[ \Pr \left[ X<Y \right] \right]=\Pr \left[ X<Y \right]$ in the both cases.
Since $X\sim N\left( {{\mu }_{X}},\sigma _{X}^{2} \right)$ and $Y\sim N\left( {{\mu }_{Y}},\sigma _{Y}^{2} \right)$,$$X-Y\sim N\left( {{\mu }_{X}}-{{\mu }_{Y}},\sigma _{Z}^{2} \right),where\,\sigma _{Z}^{2}:=\sigma _{X}^{2}+\sigma _{Y}^{2}-\operatorname{cov}\left( X,Y \right).$$
We get $$\Pr \left[ X<Y \right]=\Pr \left[ X-Y<0 \right]=\Pr \left[ {\left( X-Y-\left( {{\mu }_{X}}-{{\mu }_{Y}} \right) \right)}/{{{\sigma }_{Z}}}\;<{-\left( {{\mu }_{X}}-{{\mu }_{Y}} \right)}/{{{\sigma }_{Z}}}\; \right]=\Phi \left( {-\left( {{\mu }_{X}}-{{\mu }_{Y}} \right)}/{{{\sigma }_{Z}}}\; \right)$$
where $\Phi \left( {} \right)$ is the C.D.F of the standard normal distribution.
Finally we get $\mathbb{E}\left[ \Pr \left[ X<Y \right] \right]=\Phi \left( {-\left( {{\mu }_{X}}-{{\mu }_{Y}} \right)}/{{{\sigma }_{Z}}}\; \right)$.
When ${{\mu }_{X}}={{\mu }_{Y}}=0$ as your case, $\mathbb{E}\left[ \Pr \left[ X<Y \right] \right]=\Phi \left( 0 \right)={1}/{2}\;.$
Furthermore, even if neither $X$ nor $Y$ are normal distributions, $\mathbb{E}\left[ \Pr \left[ X<Y \right] \right]={1}/{2}\;$ holds only if $X-Y$ is a symmetrical distribution with 0 mean.