I was looking at this question, and while thinking that it's a very interesting question, I thought I would not be able to provide an answer.
Then I read a comment by @coffeemath:
Things are more complicated, in that there are six ways the final roll can "go over" 50, one each from previous sums 45,46,47,48,49,50. Each of these has a different probability of being hit exactly as the value of the second last roll, and the setup is not symmetric. – 2013-05-03 06:26:36
which prompted my response:
'...there are six ways the final roll can "go over" 50, one each from...' this is not actually correct. From 45 there is one way to go over 50: rolling a 6. But from 49 there are 5 ways to go over 50: rolling 2-6. You are correct that the probability is different for each. – 2013-05-04 16:24:33
This got me to thinking about the question.
So I will not have to keep repeating it over and over here or in the comments, I'll say it once here...
We are talking about rolling one 6-sided die, so the possible numbers that will come up on any roll will be a number from 1-6 (inclusive), and the die is a "fair" (balanced) die meaning it is not weighted in such a way that would favor any number over any other number.
Next, a clarification... we are not talking specifically (exclusively) about probability. Although probability has a part in this, if we were talking exclusively about probability then the answer would be clear... on any next roll (which may be your last roll) of the die, the probability that it will be any particular number from 1-6 is the same as it is for any other number from 1-6... it is (not surprisingly) 1 in 6 (or 1/6).
So even if the last five numbers you have rolled are all 3's (33333), the probability that the next number you roll will be a 3 is the same as any of the other numbers, 1/6.
Now, you might say... whoa! the chance of rolling six 3's in a row is astronomical! Well, maybe, but consider that in this example case, you have already rolled five 3's in a row! That in itself is quite a feat. So, it's not a stretch to to consider that your next roll might just happen to be a 3. The previous five numbers that you have rolled, whether it's "33333" or "16352" (or any other five digit sequence) are already done, they have already happened, you can't change that, probability has no part in it (anymore). You could say, in a "figurative" sense, that the probability is 100%, because, hey, there it is, "33333", it did happen. The next number is independent of what has already happened, and is just as likely to be a 3, as a 2 or a 5, or any of the other numbers from 1-6.
OK, so we are talking about the "expected value" of the final roll.
Lets look at the list of possible sums, just before the final roll. The candidates are:
45, 46, 47, 48, 49, 50
We'll call them, "pre-final" sums (the sum before the final roll).
Values below 45 are not candidates for being in the list of pre-final sums because there are no numbers that can be rolled (1-6) that will increase the sum to be greater than 50.
Likewise, values above 50 are not candidates for being in the list of pre-final sums because these sums are already over 50 so for these sums, the final roll has already been made.
Here is a table showing all the possible combinations of pre-final sums, plus the numbers 1-6 (value of the next roll/possible final roll), and the possible resulting sums.
na na na na na 45+1 = 46
na na na na 45+2 46+1 = 47
na na na 45+3 46+2 47+1 = 48
na na 45+4 46+3 47+2 48+1 = 49
na 45+5 46+4 47+3 48+2 49+1 = 50
45+6 46+5 47+4 48+3 49+2 50+1 = 51
46+6 47+5 48+4 49+3 50+2 x = 52
47+6 48+5 49+4 50+3 x x = 53
48+6 49+5 50+4 x x x = 54
49+6 50+5 x x x x = 55
50+6 x x x x x = 56
Table positions containing na are not candidates for being in the list of pre-final sums because they are below 45.
Table positions containing x are not candidates for being in the list of pre-final sums because they are already above 50.
Note that each of the values for the pre-final sums, and each of the values for the next roll occur equally as often.
Now, we eliminate the cases where the resulting sum is less than 51, because these are not "final rolls"... they will require at least one additional roll for the sum to exceed 50.
What remains is the table representing all possible "final rolls":
45+6 46+5 47+4 48+3 49+2 50+1 = 51
46+6 47+5 48+4 49+3 50+2 x = 52
47+6 48+5 49+4 50+3 x x = 53
48+6 49+5 50+4 x x x = 54
49+6 50+5 x x x x = 55
50+6 x x x x x = 56
=================================================
6 5 4 3 2 1 21
28.5% 23.8% 19.0% 14.2% 9.5% 4.8%
To find the "expected value" of the final roll, we need to find the mean of all the possible final rolls...
There are 21 possible final rolls. Now we compute the weighted average to find the mean:
$6 + 5 + 4 + 3 + 2 + 1=21$
$(6 * 6)+(5 * 5)+(4 * 4)+(3 * 3)+(2 * 2)+(1 * 1)=91$
$\frac{91}{21} = 4\frac{1}{3}$
The "expected value" of the final roll is $4\frac{1}{3}$