The definitions are as follows:
- A relation $R$ on a set $X$ is symmetric if for all $a, b \in X$, $aRb$ implies $bRa$.
- A relation $R$ on a set $X$ is non-symmetric if it is not symmetric; i.e. there exist $a, b \in X$ such that $aRb$ does not imply $bRa$.
- A relation $R$ on a set $X$ is called antisymmetric if for all $a, b \in X$, $aRb$ and $bRa$ implies $a = b$.
One can see that non-symmetric and antisymmetric relations are quite different through easy examples. One stock of examples for antisymmetric relations is given by directed graphs; take $X = \{1,2,3,4\}$ to be the set of vertices of graph and define the relation $R_1$ on $X$ as follows: $$a R_1 b \iff \text{there is a directed edge from } a \text{ to }b.$$ A concrete example witnessing non-symmetricity for $R_1$ would be the following graph: $$\require{AMScd}\begin{CD}
1 @>>> 2\\
@VVV @VVV\\
3 @>>> 4
\end{CD}$$ Then $R_1$ is non-symmetric, since $2 \to 4$ (i.e. $2R_14$) but $4 \not\to 2$ (i.e. it is not the case that $4 R_1 2$).
Finally, for antisymmetric relations you can take any partial order on a set, such that the standard $\leq$ relation on the integers or the reals, say.