You can define $E=\{(x,y)\in 5\mathbb Z\times 5\mathbb Z\mid x+y\in5\mathbb Z\}$
The question resumes to show that $E$ is the whole space, i.e. " does $E=5\mathbb Z\times 5\mathbb Z$ ? " since this happen to be always true.
Conversely with $E^\complement=\{(x,y)\in 5\mathbb Z\times 5\mathbb Z\mid x+y\notin5\mathbb Z\}$ this is equivalent to $E^\complement=\varnothing$.
An alternative writing could be:
- let $x\in 5\mathbb Z+5\mathbb Z$, show that $x\in 5\mathbb Z$
- or show $5\mathbb Z+5\mathbb Z\subset 5\mathbb Z$ in pure set notation
And you can rewrite the set (in the set builder notation) $5\mathbb Z+5\mathbb Z=\{a+b\mid a\in 5\mathbb Z,\ b\in 5\mathbb Z\}$