Consider IID $X_1, \ldots, X_n$. Consider $Y = X_1 + \ldots + X_n$
What is the formal reason why $Y \neq nX_i$?
I tried to explain this to a younger student by saying something like "they're random variables, so you can't add them in that way because the randomness means they aren't guaranteed to have the same realization. If they were guaranteed to be IID AND also have the same value, then you can add them."
Then I give an example where $X \in \{0, 1\}$. If we use $Y = X_1 + X_2$, then $ \in \{0,1,2 \}$, but if we use $Y = 2X_1$, then $Y \in \{0, 2\}$.