The actual Hessian is the negative of what you show.
The determinant of the Hessian is negative. Therefore, the Hessian has one negative eigenvalue and one positive eigenvalue. The Hessian is indefinite. The Hessian is NOT positive semidefinite.
Therefore, $f(x,y) = \frac{x}{y}$ is neither convex nor concave.
Edit: Your mistake is using the same (x,y) in the quadratic form that you use in the calculation of the Hessian. That is not correct. The correct way is to choose an (x,y), calculate the Hessian $H$ at that (x,y), and then consider any $(x^*,y^*)$ at which to evaluate the quadratic form $(x^*;y^*)^TH(x^*;y^*)$. You will see that for some choices of $(x^*;y^*)$, the quadratic form is negative, for others it is positive, and for others, it is zero.