Generally speaking most QR codes look as though they have about 50% of their cells black. If a putative QR code had 90% or 10% of its cells black, we would reasonably conclude that it didn't look like a QR code. Centred on the mean, which may possibly not be 50%, in what interval must the percentage of black squares fall in order to capture 95%, 99%, and 99.9% of possible QR codes? I intend "possible" to mean "appearing for normal purposes", which I realise is open-ended. If it is necessary to assume a certain size, please use version 1, which defines a 21 x 21 cell array.
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Having said that, are you hung up on getting a mathematical proof? If not, you could try an empirical approach with samples of QR codes and statistical analysis of the blact/white ratio of those. I am assuming this is not an exercise in theory and you want to solve this for addressing a practical problem.
– vvg Oct 21 '20 at 18:53