We have two facts: first $mS=S\cap mR$; second
$$
\frac{S}{mS}=\frac{S}{S\cap mR}\cong\frac{S+mR}{mR}
$$
so all you need to know is that $S+mR=R$.
You have the additional information that $[R:S]=n$ (index as abelian groups), so in particular $nr\in S$ for all $r\in R$. Now we can write
$$1=nx+my$$
for suitable integers $x$ and $y$; thus, if $r\in R$,
$$r = 1r = (nx+my)r = n(xr)+m(yr),$$
which shows that $r\in S+ mR$.
Why is $nR\subseteq S$? You have the abelian group $(R,+)$ and its subgroup $S$ that has index $n$, meaning that
$$
\left|\frac{R}{S}\right|=n.
$$
Thus the group $A=R/S$ has $n$ elements, which means that $nx=0$, for any $x\in A$ (I'm using additive notation, of course): this is just the same as saying that $nr\in S$ for all $r\in R$.