You can prove it by induction on the number of vertices in the tree. Suppose that it’s true for all trees with fewer than $n$ vertices, and $T$ is a tree with $n$ vertices. Let $u$ be a vertex of $T$ of degree $\Delta$, and let $u_1,\ldots,u_\Delta$ be the vertices adjacent to $u$. For $k=1\ldots,\Delta$ let $T_k$ be the subtree of $T$ induced $u$, $u_k$, and all of the vertices $w$ of $T$ such that the path from $w$ to $u$ goes through $u_k$.
Each of these trees has fewer than $n$ vertices, so the result holds for each of them. Collectively they have the same number of vertices of degrees $2$ through $\Delta-1$ as $T$, one fewer vertex of degree $\Delta$, and $\Delta$ more vertices of degree $1$, so
$$v_1+\Delta=\sum_{k=3}^\Delta(k-2)v_k-(\Delta-2)+2\Delta\,.\tag{1}$$
The numbers $v_k$ are the vertex counts for $T$. The $\Delta$ on the left is for the new vertices of degree $1$. The $\Delta-2$ on the right accounts for the loss of a vertex of degree $\Delta$. And the $2\Delta$ is the extra $+2$ terms in the $\Delta$ equations for the trees $T_1,\ldots,T_\Delta$.
Simplifying $(1)$ yields the desired result for $T$:
$$v_1=\sum_{k=3}^\Delta(k-2)v_k+2\,.$$