I used the method of induction to prove this.
For the basis step, when $n=4$, the statement is $[2(4)]!≥10^4$ which is the same as $40320≥10000$ which is true.
Next, for the inductive step, we show $\mathrm{S}_k$ implies $\mathrm{S}_{k+1}$ for some integer $n=k≥1$.
By assuming that $(2k)!≥10^k$ is true. Therefore, we need to show $(2k+2)!≥10^{k+1}$ for $n=k+1$. First, $10^{k+1}=10\cdot10^k$. By the induction hypothesis, $(2k)!≥10^k$, so $10\cdot(2k)!≥10\cdot10^k$.
Since $k≥4$, we know that $2(k+1)≥10$. So, $2(k+1)\cdot(2k)!≥10\cdot10^k$ by substitution. This simplifies to $(2(k+1))!≥10\cdot10^k$ which equals $(2(k+1))!≥10^{k+1}$ which we needed to show.
I know my expansion from $2(k+1)(2k)!$ to $(2(k+1))!$ is wrong, but I don't know what the correct way to get to $(2(k+1))!$ from $2(k+1)(2k)!$.