There is. It uses the fact that the conformal automorphisms of the complex plane are the nonconstant linear polynomials $z\mapsto az+b,~a\neq0$. These are Möbius transformations.
Now let $\varphi:\overline{\mathbb C}\longrightarrow \overline{\mathbb C}$ be a conformal automorphism of the Riemann sphere. Let $a:=\varphi^{-1}(\infty)$. We consider two cases:
1: $a=\infty$
Then $\varphi\vert_{\mathbb C}$ is a conformal automorphism of the complex plane, so it is a Möbius transformation defined on $\mathbb C$. Since the conformal extension to $\overline{\mathbb C}$ is unique, $\varphi$ itself is also a Möbius transformation.
2: $a\neq\infty$
Then consider the Möbius transformation
$$\mu(z):=\frac{az+1}{z},$$
which sends $\infty$ to $a$. Then $\varphi\circ\mu$ is a conformal automorphism of $\overline{\mathbb C}$ which sends $\infty$ to $\infty$, so this automorphism belongs to case 1, and is thus a Möbius transformation. But then since Möbius transformations are a group, $\varphi\circ\mu\circ\mu^{-1}=\varphi$ is also a Möbius transformation.
The fact from the beginning (automorphisms of the complex plane) can be proved using Casorati-Weierstraß to show that in injective entire function must be a polynomial, and the fundamental theorem of algebra to show that to be injective, the polynomial must also be of degree 1.