Below I'm assuming that "syntactically inequivalent" is a typo for "semantically inequivalent," since otherwise as GVT commented above the problem is trivial.
In fact, there can never be such a $\psi$ - essentially, no nontrivial infinite conjunction is ever expressible by a first-order sentence.
To see this, suppose otherwise and consider the theory $$T=\{\neg\psi\}\cup\{\varphi_i:i\in\mathbb{N}\}.$$ If this is finitely satisfiable, then by compactness it is satisfiable and any model of $T$ witnesses $\{\varphi_i:i\in\mathbb{N}\}\not\models\psi$. So we just need to show that $T$ is finitely satisfiable.
Suppose $T_0\subset T$ is finite. WLOG, $T_0$ has the form $\{\neg\psi\}\cup\{\varphi_i: i\le n\}$ for some $n$. By assumption on the $\varphi_i$s, this is semantically equivalent to the sentence $\neg\psi\wedge\varphi_n$. Now if $\neg\psi\wedge\varphi_n$ were unsatisfiable, this would mean $\varphi_n\models\psi$. But since $\psi\models\varphi_i$ for every $i\in\mathbb{N}$ this would give e.g. $\varphi_n\models\varphi_{n+1}$, which - since $\varphi_{n+1}\models\varphi_n$ by assumption - would imply $\varphi_n\equiv\varphi_{n+1}$, contradicting the assumed inequivalence.
(Note that I'm writing e.g. "$\varphi_{n+1}\models\varphi_n$" instead of "$\models\varphi_{n+1}\rightarrow\varphi_n$." Of course, these are equivalent, and I find the former easier to think about.)