If $f$ is twice differentiable on $[1,7]$, then it must be differentiable on $[1,3]$ and $[3,7]$. Applying the mean value theorem to each interval then implies that there exists an $x_1\in(1,3)$ and an $x_2\in (3,7)$ such that
$$f'(x_1)=\frac{f(3)-f(1)}{3-1}=\frac{f(3)-f(1)}{2}$$
and
$$f'(x_2)=\frac{f(7)-f(3)}{7-3}=\frac{f(7)-f(3)}{4}$$
But $f(7)=3f(3)-2f(1)$ implies that $f(7)-f(3)=2f(3)-2f(1)$, so
$$f'(x_2)=\frac{f(7)-f(3)}{4}=\frac{2f(3)-2f(1)}{4}=\frac{f(3)-f(1)}{2}=\frac{f(3)-f(1)}{3-1}=f'(x_1)$$
We thus have $f'(x_1)=f'(x_2)$, and since $f$ is twice differentiable on $[x_1,x_2]\subset[1,7]$, it must be the case that $f'$ is differentiable on $[x_1,x_2]$. We can now apply Rolle's theorem to $f'$ on the interval $[x_1,x_2]$ to deduce that there is a $c\in(x_1,x_2)\subset(1,7) $ where $f''(c)=0$. And that's what we wanted!