The integral converges. There is potential trouble at $0$ and "at" infinity. So we split the integral into (i) the part from $0$ to $1$, and (ii) the part from $1$ to $\infty$.
(i) Look at the power series expansion of $2-2\cos x-x\sin x$. The first few terms are $2-2\left(1-\frac{x^2}{2!}+\frac{x^4}{4!}\right) -x\left(x-\frac{x^3}{31}\right)$. There is cancellation, and the first non-zero term is the $x^4$ term. So our function behaves well as $x$ approaches $0$ from the right: It approaches $\frac{1}{12}$. If we define your integrand to be $\frac{1}{12}$, the resulting function is continuous on $[0,1]$, and hence integrable.
(ii) For large $x$, the integrand is $\lt \frac{K}{x^3}$ for some constant $K$, and we know that $\int_1^\infty \frac{dx}{x^3}$ converges.