We can easily verify(by the definition of complex addition and multiplication) that
$$
\overline{w+z}=\bar{w}+\bar{z} \text { and } \overline{w z}=\bar{w} \bar{z}
$$
Here's a stronger version of your claim.
Theorem(Polynomials with real coefficients have roots in pairs). Suppose $p\in \mathcal P(\mathcal C)$ is a polynomial with real coefficients. If $\lambda \in \mathbb C$ is a root of $p$, then so is $\bar \lambda $.
Proof. Let
$$
p(z)=a_{0}+a_{1} z+\cdots+a_{m} z^{m}
$$
Assume $\lambda$ is a root of the polynomial, then
$$
a_{0}+a_{1} \lambda+\cdots+a_{m} \lambda^{m}=0
$$
Take the complex conjugate of both sides of this equation, obtaining
$$
a_{0}+a_{1} \bar{\lambda}+\cdots+a_{m} \bar{\lambda}^{m}=0
$$
so $\bar \lambda$ is also a root of $p$.
The polynomial mentioned in your case is $z^5=1$, thus for one of its roots $\lambda$, $\bar \lambda$ is also a root of $z^5=0$.