The way to see this is as follows: you must observe that
$$|f(x)| = \begin{cases}
f(x), & f(x) \geq 0 \\
-f(x), & f(x) < 0\text{.}
\end{cases}$$
It does not matter where the equality sign goes (i.e., $\geq$ as opposed to $>$, or $<$ as opposed to $\leq$) in the vast majority of situations.
We thus have
$$|x + 1| = \begin{cases}
x + 1, & x + 1 \geq 0 \\
-(x+1), & x + 1 < 0
\end{cases} = \begin{cases}
x + 1, & x \geq -1 \\
-x - 1, & x < -1
\end{cases}$$
$$|x - 1| = \begin{cases}
x - 1, & x - 1 \geq 0 \\
-(x - 1), & x - 1 < 0
\end{cases} = \begin{cases}
x - 1, & x \geq 1 \\
-x + 1, & x <1\text{.}
\end{cases}$$
Next, we must add these functions together.
First, observe that $|x + 1|$ is defined piecewise over the intervals $(-\infty, -1)$ and then $[-1, \infty)$. These are indicated by the blue and red below respectively.
For $|x - 1|$, we must look at $(-\infty, 1)$ and then $[1, \infty)$. These are indicated by the orange and green below respectively.
Apologies for my art skills.

Given the above, it is clear that the sum of $|x + 1|$ and $|x- 1|$, as a piecewise function, must have three components:
- The blue-orange one, in $(-\infty, -1)$
- The red-orange one, in $[-1, 1)$
- The red-green one, in $[1, \infty)$.
The blue-orange component is when $x < -1$, or $|x + 1| = -x - 1$ and $|x - 1| = -x + 1$. Thus the sum of these is $-x - 1 + (-x + 1) = -2x$.
The red-orange component is when $-1 \leq x < 1$, or $|x + 1| = x + 1$ and $|x - 1| = -x + 1$. Thus the sum of these is $x + 1 + (-x + 1) = 2$.
The red-green component is when $x \geq 1$, or $|x + 1| = x + 1$ and $|x - 1| = x - 1$. Thus the sum of these is $x + 1 + (x - 1) = 2x$.