Reconsider what it means for an object $\star$ to have a mass $5 kg$?
$$\begin{align*}
\text{mass of }\star &= 5\cdot \text{mass of something of }1kg\\
\frac{\text{mass of }\star}{\text{mass of something of }1kg} &= 5
\end{align*}$$
And what it means for 1 kilogram to be equal to 2.2 pounds?
$$\begin{align*}
\text{mass of something of }1kg &= 2.2\cdot\text{mass of something of }1lb\\
\frac{\text{mass of something of }1kg}{\text{mass of something of }1lb} &= 2.2\\
\end{align*}$$
So if you know $y\ lb$ and $5kg$ both represent the mass of object $\star$, then
$$\begin{align*}
y &= \frac{\text{mass of }\star}{\text{mass of something of }1lb}\\
&= \frac{\text{mass of }\star}{\text{mass of something of }1kg} \cdot \frac{\text{mass of something of }1kg}{\text{mass of something of }1lb}\\
&= 5 \cdot 2.2
\end{align*}$$
You can say one of the followings:
$$\begin{align*}
y:5 &= 2.2:1\\
y:5 &= kg:lb\\
y\ lb: 5kg &= 1:1
\end{align*}$$